Jan,
Disclaimer: I haven't used stand.Sol.
Broadly speaking in SEM, the unstandardized solution should be used for hypothesis tests.
Consider that the unstandardized path coefficient is a single parameter estimate with its standard error.
The standardized path coefficient is that estimate, multiplied by another point estimate treated as an exact value, and divided by yet another point estimate treated as an exact value.
So the standardized estimate has much more room for deviation from the population value built into it.
That said, that large a discrepancy is unusual and might warrant further investigation (e.g., are the standard errors of the variance estimates very large).
Pat