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My experience matches Patrick's: rims break in after awhile. To help this along, I have run some fine sandpaper tangentially along the break surface of a new squeeky rim. I think it helped a bit, but it just took some time in use to make it behave properly.
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Polished sidewalls tend to not brake as well until they've worn in a bit. They're also more likely to squeal. A Scotchbrite pad or something like it was a traditional approach to addressing this back in the days of shiny rims; dragging the brakes on a wet, perhaps slightly muddy ride will usually also do the trick. Or just ride 'em. I find my old MA2 rims- shiny all around with just a bit of dulling on the sidewalls from braking- stop as well as my rims with machined sidewalls.
Also, if the brake pads were used with other wheels previously, taking a file and cleaning the braking surfaces down to bare pad material may help. The aluminum dust and other dirt ground in the the braking surface may reduce the coefficient of friction, similar to glazing car brake pads.