That only works if your user has a PDF plugin installed.
Assuming they do, just create a standard link
<a href="/somePdf.pdf" target="_blank">Click here to see a PDF of all
this</a>
As long as your webserver returns the right mimetype (application/pdf
or whatever it is), that'll work fine, and for those without a PDF
plugin, it'll pop up a download dialog.
Detecting the existence of a PDF plugin, or sending the user to an
appropriate download link, is entirely OS *AND* browser dependent and
will take you many days of pain. If you want to go there, that's fine,
but you may have more success by asking on other newsgroups; at that
point it's no longer GWT related.