That is not possible (as far as I know). The whole idea with convex conic optimization is the fact that the dual lives in the same cone as the constraint, i.e., in the matrix world for matrix inequalities.
Your motivation is a bit backwards. We cannot solve max(eig(LMI))<= 0 problems in scalar form easily. Instead, we restrict the matrix LMI to be Hermitian, and write it as the cone constraint LMI <= 0