Hi,
The Newton method is a numerical algorithm and will always return just one root, if any. To find another root you have to start your search in it's vicinity, eg
Newton(Tan(x)-x,x,4.3,1e-10)
will return 4.493409457909064175, where
Tan(4.493409457909064175)-4.493409457909064175
yields -0.148638790869329223e-17.
Sorry for such late reply,
Grzesiek