Hi!
It is unclear to me what you actually want to do here.
First of all
PermuteIndices will only produce one index permutation. You need to give a list of indices to permute and description of the permutation. For instance the following swaps the first two indices in your list, i.e. alpha and beta:
PermuteIndices[T[\[Alpha],\[Beta],\[Kappa]] T[\[Lambda],-\[Beta],-\[Kappa]] CD[-\[Lambda]][CD[-\[Alpha]][\[Phi][]]],IndexList[\[Alpha],\[Beta],\[Kappa],\[Lambda]],Cycles[{1,2}]]
If you want to symmetrize over a list of indices, you can for instance do
Symmetrize[T[\[Alpha], \[Beta], \[Kappa]], IndexList[\[Alpha], \[Beta], \[Kappa]]]
This will produce 1/6 of the sum you listed.
If you apply ToCanonical to this you get zero due to the antisymmetry of the last two indices. This is not what you suggested.
However, if you apply ToCanonical to
Symmetrize[T[\[Alpha], \[Beta], \[Kappa]] T[\[Lambda], -\[Beta], -\[Kappa]], IndexList[\[Lambda], \[Alpha]]] CD[-\[Lambda]][CD[-\[Alpha]][\[Phi][]]]
you will get
T[\[Alpha], \[Beta], \[Kappa]] T[\[Lambda], -\[Beta], -\[Kappa]] CD[-\[Lambda]][CD[-\[Alpha]][\[Phi][]]]
Perhaps if you can put it into context what you want to do and why we can help you find a way to do it. When you do calculations in xAct it is sometimes better to do things in different ways compared to hand calculations.
Regards
Thomas