The key and certificate are stored in the keystore that was used to obtain the certificate.
For example, if the following command was used to obtain the certificate, then the key and certificate would be stored in the file that backs the serverKS key-store under the alias server:
/subsystem=elytron/key-store=serverKS:obtain-certificate(alias=server,domain-names=[www.example.org],certificate-authority-account=myLetsEncryptAccount,agree-to-terms-of-service)
If you need to export the certificate to a .crt file, the following command could be used:
/subsystem=elytron/key-store=serverKS:export-certificate(alias=server, path=YOUR_PATH)