Hi,
There is no limit in the extension. The CSV export function is using a lot of memory because it has to be created the CSV file in memory and only then it can be downloaded. This is a limitation of JavaScript language and chrome browser.
Can you send me a screenshot of any errors you are receiving? The errors might happen in extensions background page or in the web scraper developer tools tab. Here is how you can get the errors:
1. go to "manage extensions" panel
2. check "Developer mode"
3. find web scraper
4. open background page
5. open console tab
6. export the csv and check for errors in the console
1. Open web scraper tab in developer tools
2. click and hold to undock developer tools to a window (image)

3. Open another developer tools window by pressing CTRL+SHIFT+I in the web scraper tab. (For mac it's Cmd+Opt+I)
4. export the csv from the first developer tools window. Any errors that will happen in the web scraper tab will be printed in the other developer tools window.