They are often the same, or within a fraction of a degree or two.
I've just passed the Kew Gardens figure on to Colin for the extremes list (the extras list). You'll see from that tonight (and on many nights) that the top 10 are incredibly close. The idea that heathrow stands out hotter than other sites is a myth - it may come top quite often, but not by much. Kew Gdns is a sheltered sun-trap, probably more sheltered than H .
Julian