When there is an ENE wind alingned with the peninsula you'd expect some convergence along the spine of Cornwall.
However, days like today it is not enough to generate cloud, but what often happens is as the airflow down the English and Bristol Channels converge off Lands End, the resultant cloud can effect Scilly.
Satellite 2:30 & 4:00 PM
Basically cloudless over Cornwall, but on Scilly, well away from the more typical land based convectional cloud.
Absolutely glorious in Penzance today. Maximum of 20.2C yesterday, 20.1C today.
Graham
Penzance