It's just not that simple. (I'm ex-MO, and was discussing this with a current employee yesterday.)
I'm not convinced any one person in the MO has a complete understanding of their own networks, at least anyone who's willing to do anything useful with the data. Beyond the synop sites are a range of other observatories. Some are Climate Data Loggers, others Voluntary Observer sites. The CDLs are, iirc, all now AWSs, and all report at least hourly. They usually don't report all the standard parameters, and often have non-standard siting (e.g. a 5m anemometer mast). The VO sites at the most basic level depend upon volunteer observers (sometimes members of the public but often public bodies like councils and the Forestry Commission) submitting monthly data via the WOW website, but I think a number of those sites actually have MMS equipment (the Met Office data logging, transmission, and collation kit) and are reporting in near-real-time, like the synop and CDL sites. Bizarrely, there is no single ID number used across all types of site. Instead there are at least four different identifiers in use, each with a different length.
All the data goes through electronic real-time quality control. There's also manual checking of the data (mainly as make-work for staff in small remote MO outposts like Camborne). It all ends up in a massive database called MIDAS which is expensive and slow to query. What's for sure is that the data is not used to its full potential. It's a right mess, but "it's the way it's always been done", and no managers are informed enough to realise the potential value.
Certainly MeteoGroup makes much better use of the data which it receives from the MO, as exemplified by WeatherCast. Guess who makes more money from observation data... I suspect MeteoGroup gets its data via remote access to MIDAS on a commercial basis. They then use the data in ways the MO can't or won't, and profit accordingly.
Dan