You can detect USB device unplug or disconnection events by monitoring the Microsoft-Windows-DriverFrameworks-UserMode/Operational event channel, which logs USB device plug-and-play events.
To do this, you need to configure the Windows agent to monitor this event channel. Add the following localfile configuration to the Wazuh agent configuration file:
File location: C:\Program Files (x86)\ossec-agent\ossec.conf
You can also deploy this configuration using centralized agent configuration. Please refer to the Wazuh documentation for guidance on centralized configuration.
After applying the configuration, restart the Wazuh agent to apply the changes.
Reload the Wazuh manager ruleset to apply the new rule.
Once this is done, disconnect a USB device from the Windows endpoint to trigger the alert.
I have tested this configuration in my environment, and it is working as expected. I have also attached a screenshot for your reference.

Currently, we cannot show the deviceDescription in the alert because this field is not available in the Windows eventchannel log. As a result, Wazuh cannot display it in the alert.
The Windows Event ID 2102, which is used to detect USB device disconnection, only contains the device ID. It does not include the device description. Therefore, at this time, it is not possible to display the deviceDescription in the alert.