Dear Fernanda and Stavroula,
Unfortunately, the Unitex/GramLab manual does not presently mention any inflection operator that would add an acute accent on a vowel.
You have to make a distinct graph for each vowel. To reach and accent the last vowel before ar, you can use LL<e$>é$, LL<a$>á$, LL<i$>í$ and so on (manual, section 3.5.2), and LLL<i$>í$i for aliviar, and so on.
An operator adding an acute accent on a vowel would allow you to conflate several inflection classes in Spanish, since it would apply to all vowels. But then you would also need to reach the last vowel before the infinitival suffix, and the solution above does not work at the same time for all vowels. So, you would have to split back the inflection class according to the number of letters between the vowel and the end of the stem, unless the <X$Y> operator (manual, section 3.5.2) is extended so that X can be a regular expression.
Best regards,
Eric Laporte