The way I read it you would need to carry a few cylinders of gas to fall into the regulated area. I'm not sure at what point is a legal requirement to carry a hazard diamond - I just carry one anyway.
Good advice is to keep a gap open in the top of the vehicle (for lighter than air gasses) if you are holding the cylinders in there for any length of time - just in case there is a small leak and buildup of gas. Obviously check and correct any leaks.
I always use my Helium/Hydrogen cylinders laying down for use - so they can't be knocked over. You are supposed to transport the bottles lashed & standing up - as in the event of an accident the valves stand less chance of being knocked off. I was advised if you can't do that due to cylinder length then arrange the cylinder so that it is propelled away from you in the case of a serious accident. Personally I think with hydrogen in this situation you be better putting your head between your legs - so you can kiss your ass goodbye ;-).
The only problem with fast dump of gas I've noticed is that quick connects have a habit of leaking slightly or not mating properly when cold.