Originally, I was puzzled as to why oven springs "weaken" in service,
because they don't get very hot. Motorcyclists from the old days will be
familiar with the need to replace valve springs because they shorten in
service, particularly the exhaust ones. I'd always assumed this was
because of a high temperature process, creep. Performance engines use
expensive nimonic exhaust valves for the same reason.
A metallurgist with a production engineering background tells me the
relaxation is actually caused by plastic deformation around microcracks
and other defects