Hello Tim,
It sounds like you are running into a known issue with regards to missing imports in your collections (since EDG is starting without any issue in a clean workspace, but not after you import your projects). Adding the missing imports, or removing the collections that have missing imports should resolve the issue and allow you to experience the new features present in TopBraid 7.0. You can verify this is the case by going to the Server Administration page after encountering the 404 error (in an environment with the projects uploaded from your version 6.4.1 workspace), and removing the projects. After removing the project(s) with missing imports, you should be able to access EDG. Sorry for the inconvenience and thank you for your interest in the new version.
Regards,
James Koban
TopQuadrant Support