Thanks, I can see that is what is happening, although I am still a little unsure why the PpY effects the answer when Pmt is 0. After some further exploring it seems the best way to tackle this problem is actually:
N=4 and PpY=1, and CpY=12
My confusion stems from this double use of 'Payment', to indicate both money paid in/out of the account regularly and also its effect on the Interest rate... I am fairly happy that I understand what it is doing... I'm just not quite clear in my head as to why...