Probably not the answers you were hoping for, but here they go:
1. There are no such libraries defined (because nobody thought of
defining them until now!); you can define a set of functions as a
library and access them from the catalog; there's a shortcut function
to enter function names like "physics.ohm()", instead of
physics_library\ohm()
2. Nspire CAS doesn't have soft (programmable) menus.
But there's a faster way to convert between bases: 0b01000111010>Hex
will display in hex base, regardless of menu settings (replace > by
the conversion symbol; from the symbol palette it's the black triangle
on the first row, between underscore and deg symbo; I don't think this
one has a shortcut or at least I couldn't find it).
You won't convert the history, though. History is static: you can
delete entries or copy&paste, but once something is in the history you
can't change it unless you repeat the calculation.
Cheers,
Nelson