My previous message can be ignored -- as Aaron pointed out (thank you!) this has been fixed, I was not using a recent-enough release. Sorry for the noise.
Python 3.9.2 (default, Mar 31 2021, 11:25:52)
[Clang 10.0.1 (clang-1001.0.46.4)] on darwin
Type "help", "copyright", "credits" or "license" for more information.
>>> import sympy
>>> from sympy import asec, Rational, acos
>>> sympy.__version__
'1.7.1'
>>> acos(Rational(1,2))
pi/3
>>> asec(Rational(2,1))
pi/3