The E stands for expanded, so the core is less dense. I'm not aware of any problem with that but it might be an idea to see it before you buy any, hopefully they'll send you a sample.
The U in both cases stands for unplasticised, which is better as it's recyclable.
If anyone's interested in the finer points of PVC... Standard plasticised PVC is more flexible and used for flooring, pipe insulation etc.
However for nestbox roofs, although it's a synthetic product, uPVC improves its environmental performance by being recyclable, doesn't need painting and, unlike single-use plastics, it's serving a purpose for decades.
For example, the industry standard BRE Green Guide to Specification rates uPVC-framed windows as A (Good) overall for environmental impact.
Regards,
Mike
Islington & Hackney Swifts Groups