Asolar cell or photovoltaic cell (PV cell) is an electronic device that converts the energy of light directly into electricity by means of the photovoltaic effect.[1] It is a form of photoelectric cell, a device whose electrical characteristics (such as current, voltage, or resistance) vary when it is exposed to light. Individual solar cell devices are often the electrical building blocks of photovoltaic modules, known colloquially as "solar panels". Almost all commercial PV cells consist of crystalline silicon, with a market share of 95%. Cadmium telluride thin-film solar cells account for the remainder.[2] The common single-junction silicon solar cell can produce a maximum open-circuit voltage of approximately 0.5 to 0.6 volts.[3]
Photovoltaic cells may operate under sunlight or artificial light. In addition to producing energy, they can be used as a photodetector (for example infrared detectors), detecting light or other electromagnetic radiation near the visible range, or measuring light intensity.
In contrast, a solar thermal collector supplies heat by absorbing sunlight, for the purpose of either direct heating or indirect electrical power generation from heat. A "photoelectrolytic cell" (photoelectrochemical cell), on the other hand, refers either to a type of photovoltaic cell (like that developed by Edmond Becquerel and modern dye-sensitized solar cells), or to a device that splits water directly into hydrogen and oxygen using only solar illumination.
Assemblies of solar cells are used to make solar modules that generate electrical power from sunlight, as distinguished from a "solar thermal module" or "solar hot water panel". A solar array generates solar power using solar energy.
Application of solar cells as an alternative energy source for vehicular applications is a growing industry. Electric vehicles that operate off of solar energy and/or sunlight are commonly referred to as solar cars.[citation needed] These vehicles use solar panels to convert absorbed light into electrical energy that is then stored in batteries.[citation needed] There are multiple input factors that affect the output power of solar cells such as temperature, material properties, weather conditions, solar irradiance and more.[4]
The first instance of photovoltaic cells within vehicular applications was around midway through the second half of the 1900's. In an effort to increase publicity and awareness in solar powered transportation Hans Tholstrup decided to set up the first edition of the World Solar Challenge in 1987.[citation needed] It was a 3000 km race across the Australian outback where competitors from industry research groups and top universities around the globe were invited to compete.[citation needed] General Motors ended up winning the event by a significant margin with their Sunraycer vehicle that achieved speeds of over 40 mph.[citation needed] Contrary to popular belief however solar powered cars are one of the oldest alternative energy vehicles.[5]
Current solar vehicles harness energy from the Sun via Solar panels which are a collected group of solar cells working in tandem towards a common goal.[6] These solid-state devices use quantum mechanical transitions in order to convert a given amount of solar power into electrical power.[6] The electricity produced as a result is then stored in the vehicle's battery in order to run the motor of the vehicle.[6] Batteries in solar-powered vehicles differ from those in standard ICE cars because they are fashioned in a way to impart more power towards the electrical components of the vehicle for a longer duration.[citation needed]
Multiple solar cells in an integrated group, all oriented in one plane, constitute a solar photovoltaic panel or module. Photovoltaic modules often have a sheet of glass on the sun-facing side, allowing light to pass while protecting the semiconductor wafers. Solar cells are usually connected in series creating additive voltage. Connecting cells in parallel yields a higher current.
However, problems in paralleled cells such as shadow effects can shut down the weaker (less illuminated) parallel string (a number of series connected cells) causing substantial power loss and possible damage because of the reverse bias applied to the shadowed cells by their illuminated partners.[citation needed]
Although modules can be interconnected to create an array with the desired peak DC voltage and loading current capacity, which can be done with or without using independent MPPTs (maximum power point trackers) or, specific to each module, with or without module level power electronic (MLPE) units such as microinverters or DC-DC optimizers. Shunt diodes can reduce shadowing power loss in arrays with series/parallel connected cells.
The photovoltaic effect was experimentally demonstrated first by French physicist Edmond Becquerel. In 1839, at age 19, he built the world's first photovoltaic cell in his father's laboratory. Willoughby Smith first described the "Effect of Light on Selenium during the passage of an Electric Current" in a 20 February 1873 issue of Nature. In 1883 Charles Fritts built the first solid state photovoltaic cell by coating the semiconductor selenium with a thin layer of gold to form the junctions; the device was only around 1% efficient.[10] Other milestones include:
Solar cells were first used in a prominent application when they were proposed and flown on the Vanguard satellite in 1958, as an alternative power source to the primary battery power source. By adding cells to the outside of the body, the mission time could be extended with no major changes to the spacecraft or its power systems. In 1959 the United States launched Explorer 6, featuring large wing-shaped solar arrays, which became a common feature in satellites. These arrays consisted of 9600 Hoffman solar cells.
By the 1960s, solar cells were (and still are) the main power source for most Earth orbiting satellites and a number of probes into the solar system, since they offered the best power-to-weight ratio. However, this success was possible because in the space application, power system costs could be high, because space users had few other power options, and were willing to pay for the best possible cells. The space power market drove the development of higher efficiencies in solar cells up until the National Science Foundation "Research Applied to National Needs" program began to push development of solar cells for terrestrial applications.
In the early 1990s the technology used for space solar cells diverged from the silicon technology used for terrestrial panels, with the spacecraft application shifting to gallium arsenide-based III-V semiconductor materials, which then evolved into the modern III-V multijunction photovoltaic cell used on spacecraft.
In 2020, the US Naval Research Laboratory conducted its first test of solar power generation in a satellite, the Photovoltaic Radio-frequency Antenna Module (PRAM) experiment aboard the Boeing X-37.[21][22]
Improvements were gradual over the 1960s. This was also the reason that costs remained high, because space users were willing to pay for the best possible cells, leaving no reason to invest in lower-cost, less-efficient solutions. The price was determined largely by the semiconductor industry; their move to integrated circuits in the 1960s led to the availability of larger boules at lower relative prices. As their price fell, the price of the resulting cells did as well. These effects lowered 1971 cell costs to some $100 per watt.[23]
In late 1969 Elliot Berman joined Exxon's task force which was looking for projects 30 years in the future and in April 1973 he founded Solar Power Corporation (SPC), a wholly owned subsidiary of Exxon at that time.[24][25][26] The group had concluded that electrical power would be much more expensive by 2000, and felt that this increase in price would make alternative energy sources more attractive. He conducted a market study and concluded that a price per watt of about $20/watt would create significant demand.[24] The team eliminated the steps of polishing the wafers and coating them with an anti-reflective layer, relying on the rough-sawn wafer surface. The team also replaced the expensive materials and hand wiring used in space applications with a printed circuit board on the back, acrylic plastic on the front, and silicone glue between the two, "potting" the cells.[27] Solar cells could be made using cast-off material from the electronics market. By 1973 they announced a product, and SPC convinced Tideland Signal to use its panels to power navigational buoys, initially for the U.S. Coast Guard.[25]
Research into solar power for terrestrial applications became prominent with the U.S. National Science Foundation's Advanced Solar Energy Research and Development Division within the "Research Applied to National Needs" program, which ran from 1969 to 1977,[28] and funded research on developing solar power for ground electrical power systems. A 1973 conference, the "Cherry Hill Conference", set forth the technology goals required to achieve this goal and outlined an ambitious project for achieving them, kicking off an applied research program that would be ongoing for several decades.[29] The program was eventually taken over by the Energy Research and Development Administration (ERDA),[30] which was later merged into the U.S. Department of Energy.
Following the 1973 oil crisis, oil companies used their higher profits to start (or buy) solar firms, and were for decades the largest producers. Exxon, ARCO, Shell, Amoco (later purchased by BP) and Mobil all had major solar divisions during the 1970s and 1980s. Technology companies also participated, including General Electric, Motorola, IBM, Tyco and RCA.[31]
Adjusting for inflation, it cost $96 per watt for a solar module in the mid-1970s. Process improvements and a very large boost in production have brought that figure down more than 99%, to 30 per watt in 2018 [34]and as low as 20 per watt in 2020.[35]Swanson's law is an observation similar to Moore's Law that states that solar cell prices fall 20% for every doubling of industry capacity. It was featured in an article in the British weekly newspaper The Economist in late 2012.[36] Balance of system costs were then higher than those of the panels. Large commercial arrays could be built, as of 2018, at below $1.00 a watt, fully commissioned.[9]
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