In the absence of a log file to look at I am guessing here, but I think that you are using a 'DiveCAN' Shearwater CCR controller, and not an analogue monitor / controller unit?
This would explain the too high readings in the profile graph - the scaling for 'DiveCAN' units has been improved in newer versions of Subsurface and you should upgrade to the latest version.
As for the data overlay, my suspicion is that the tank used at this point in the dive is set to 'OC' in Subsurface instead of 'diluent', so the ppO2 shown is that of what you'd get if you were breathing the gas in the tank in open circuit bailout.
Ngā mihi
Michael Keller