Further, Not quite sure about HDLM but HP secure path creates a new device file for the physical disk after masking all the original disk device files, meaning when you say ioscan -fnC disk you will see only one path instead of 4 for an active/passive SAN, the path failover will be taken care by the multipathing sw.
Incase of an active/active controller, you will see all the path listed as active and you use one of the device path out of four to create VGs etc. The loadbalancing and path failover will be taken care by the multipathing sw.
In your case, since you have the VGs already created, I would take a vgexport for the VGs from SAN just as a precautionary.
I will install multipathing software.
I would check for the device file created by the multipathing software to confirm multipathing sw is actually working.
if your multipathing sw masks the path, I will just rename the /etc/lvmtab to /etc/lvmtab.old, then I will do a vgscan. End of the story.
If your multipathing sw lists the old device paths including the new one, I will take a vgexport -p -m /tmp/vgsan.map -f /tmp/vgsan.pmap.
I will edit the vgsan.pmap for the multipathing sw's device path
do a vgexport and do a vgimport using the vgsan.pmap file
I assume that your disks are not mirrored at the host side.
Kind regards...Avi