In general, no, posterior intervals will not have the correct frequentist coverage. The asymptotic
limit where everything becomes a Gaussian and the intervals do have the correct coverage is
a subtle one and unlikely to be reached in practice (otherwise we wouldn’t need all of this heavy
statistical machinery in the first place).
If you wanted to be formal then the closest you could get would be to build up posterior predictive
distributions for any transformation of the parameters of interest and compute p-values there. The
coverage won’t be correct because of the latent marginalization over parameters but it gives you
something you can at least attempt to understand from a frequentist perspective.
This also demonstrates why you’ll run into issues trying to estimate an overall effect — you’d need
a full joint distribution over the covariates in order to properly marginalize them out. I believe
post-stratification is the right approach if you did want to push ahead here.
In the end the answer you need is a political one and not a statistical one...
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