Yes, this is possible. I am using too Shelly 2.5 to control venetian blinds.
You have to define two roller shutters in Tasmota (i am using 9.2.0) using the same relay output.
The timing of the first has to be set to the full range Up/Down and the second only the time it takes to tilt the slats from Open to Closed.
After setting this up, there is a second slider visible on the Tasmota main menu which then controls the angle.
This works quite well on my Shellys but the granularity of the angle is a bit too low for my taste.
My blinds take about 45 seconds to open and the time to change the angle from open to closed is only 1.4 seconds.
I think this causes the problem as the resolution seems to be determined by the timing first shutter (but i may be wrong, i have to check the shutter code...).
I can control the angle of the slats in about 5 steps which is ok but with 10 or more the handling experience would be much better.
This should be possible as the timing resolution of Tasmota is 50ms so it should be possible to have 28 steps in 1.4 seconds.
I can send you the configuration commands if you need them.
Currently i have configured
two percentage sliders
in openHAB to send 0 to 100% for the opening to shutter1 and 0 to 100% for shutter2 for the angle and this works very well.
Gemikro