Hi Benjamin
If you boot holding down ALT on the keyboard you’ll see a list of all the boot drives available to the Mac. If the Mac scans the firewire port and sees the IcyBox enclosure it’ll ask it for any drives connected. If for some reason the IcyBox enclosure’s controller chip doesn’t respond in the correct way or doesn’t understand the boot requests, then the Mac won’t find the RAID0 (or any other boot volume) to boot from.
The Western Digital Studio Passport was a mobile FireWire800 drive marketed for use with Macs, the only problem was that it wasn’t bootable due to the chipset and firmware on the drive controller card, making it entirely useless for me.
It’s unlikely given the generic, adaptable nature of the IcyBox enclosure that it wouldn’t support booting, but installing OS X on a single drive connected to the IcyBox then booting from it will test the ‘bootability’ (if that’s a word) of the enclosure.
If you are able to boot the RAID, the fact that it’s a software RAID will slow things down, also that it’s on the FireWire800 bus will greatly hamper the speed of the drives, you might find the system to be very slow and show the spinning beachball much more than normal.
Don’t suppose your Mac’s got a thunderbolt port? If it’s the 27” 2011 iMac then you can also fit an additional internal SSD drive to boot from, then store your data on the mirrored RAID, will be like a new Mac.
Regards
Sam