It's impossible for anyone to know if your usage of Skia is safe from security issues without auditing your code.
There have absolutely been critical safety fixes in Skia between 2018 and present day that affected Chrome, but Chrome uses just about every feature that Skia has to offer, and its draws are based on HTML/CSS/Canvas commands that are freely accessible to an attacker. It's likely that your app is less flexible so you may not be exposed to these issues.
I think you should just try updating and see what happens. You will need to update some things, but it might not be as bad as you are concerned about. If it is rough, consider doing it in stages—first upgrade to M80, then to M100, then to M115, then to latest. This will take more time to do, but it should be much easier, since you probably won't encounter more than one or two broken things at a time.