Yes, any bright star would be fine for studying your optics. You might consider capturing a series of images by panning the camera/scope around to put the star in different locations of the FOV. You should be able to map the size/shape of any optical defects.
That's pretty much exactly how production lens testers work in industry. E.g. those by Tripotics. They project a test pattern through a lens and systematically move the camera around, capturing images to build up a map of the lens' sharpness, distortions, etc.
Regards,
Mike