Hi Jianing,
I just so happen to have some odd k that satisfy that constraint lying around in one of my spreadsheets I obtained while trying to hunt for numbers where σ(k)-nk is positive and within a certain bound that I have converted into two lists for you:
σ(k)/k > 4
28653392588170406505341237671920748619590125,1661623794535952315007686817731787979978125,242071729759998279081413044462473388430625,1853070540093840001956842537745897243375,10860627271287767743971868567756435705125,5320030348672254562476052286444417821521411375,1650453007278489284930103705576879531243395094375,30859951052155454708779761513788784173833560844997551871325,5320076120839568708787520437993189804450052125,6408291014834700478176804841836253757623761161004819225,2513075465915553072587475009581219002651875,6436588468472692183875689272766617167637125,27748198008684686051223192149055692101816058120255556375,263817009286091472160531845335754431875125,33323704367819273021779070662889159701708759725,19402161896044932103065918262812133480623749909636581373005588673758888352625,2239081748599958718866433291614639924255625,18288323406152096615209584797401193913331386947840787370266393675,63131165020330765552667449874112622773967108425846100597425,621594413440761589187607182043176599657125,1488295781019085787475624039623629023500625,1320409242484345866151941581259121406847706420678843246125,8636068527390334352381003657808651899252009658009979423922025,8032852581133752156797299272753436921126875,896540044254322112060865708612693239274375,10744248390079249298381878668971867688658057371681902114440970325,157367094625482157955621387833269408070941054897547972979175,1152217793609159443742128616241970014061291997568400008107475,28975190090679719722651120489137630890390478541591486160025,373303170294217561317758534468406864126185299013826166953383775,10876569458254428833303839444352002265485875,5611295823189757671496131041876310590473023939415025262197482321919133261868875,11495362521262925051975671042993205271834375,11139244257867465180302368063978146350625,189749434042796828595032649006478207600146246777733632701575575,669930202672491067748345187565360351715066625,7911204658682312327390376900272836752990375,92916591382574180034274121038457549995283133375,1366714920639445753189931277165828918970875,1094894298033961386327150736714270762673343926689632589910068793364375,25946723360890053696367815832222624980078393129489166188439575,735794933943601726977080692839655988402625,31430338501584003950911503412497931697773871034525,33630396726685436460498140217313418912923437529838593781025,31430338846848789354697303105060729981466405934675,36369299365660403010990250723488603628544625,106856756351262073257629188671224275198254121083017581192224675,31430340918437501777412101260437519683621615335575,410353468529873655398985083371243081882421154398646031914170925,342193504047841011233602301134891437077812045296751639011825,31430342644761428796341099723251511102084289836325,5894346083873629203119220218020420705634625,31430344025820570411484298493502704236854429436925,6433694347067377085445666788353733125875,3184526014338119206059488766093410969445375,8078346207890837581406005050855250345461066039478388289305133975,174492253569132699362445642414829251980126625,31430348168997995256913894804256283641164848238725,31430348859527566064485494189381880208549918039025,11458499856535317764909164905687177336375,31430349895321922275842893267070275059627522739475,1026417475695757430052231916344157254614625,47619673420261750877415116027855141168625,194072702294546996159996958363252901185375,228714557567249440845158942278546368755470875,229544949858095359355842489851995066822383780444406110200537675
σ(k)/k > 5
541241312669435437347268804215330697893940761326502763438750289807079921020765071225422988448494447313597439975005843129310598125,1083030436836249659198303729298459668423341409835989522023996455688334438903683344017407994367257799070910414450632302334345974375,326097996034073476728267918483900546722405265059526060519412603711870320121814791884433669617612838573704825029723887018125,1125297149265505185059229248942411826274372251653250601991918083285561123149757978103975627746847998315000379709049654216875,158686889546222270551603372445601690257490850132071247982385346411853736982025729007259010878869856627483940208518569351875,45454370665658723709685990669481699355919392750285081321023831159666370321532963243384035629263565709607752902046185132060401784202710934090916685625,2159790145701431758590834870146925233736076893472311474048133893200384408473801392025197038430247947667959214509458825311875,1634417674640332627739077334250186362110546553887361987342041131093930366822091714287761581362511555805818344458135300941875,32765231030368130505321066844937242590760815444336460510630176237887770948319561245495290354102667740411619243107358060501875,1089790142278439034319911491486927400603643332613175715693216533550714977724428713919473650871239286586606735468933642760748125,6600773824300260813196120602548504864109208467235174817679435588568246090660160721786581097503613624214215111206253857979375,527619585819749859848471862896747858220754776070893932822299292582372894442042225327384653499780281422067541270922752249375,25901997161768905853888764965493050286667335706371836401840811952895576592476598913995329782080452802846683794542890340039375,58348068789702541542540337556989734284405072814056808320424990206864405474468685568873748608608466827071760350234947394107813125,525856562575427462874568054130983516903335039448807697581550236686873060738244158826897701642466448973357434218104543358125,344895121559870543744997735684352013142664615231697288050276638511372144215546695148618293017174706839808268571282056635625
As for how I found them, for each k I started with a seed where
σ(k)/k is "close" to some integer n but does not exceed it and then I try to multiply primes onto it to take it past n. Hope this helps!
Best,
Alex Violette