Estefania,
You could install an OSSEC agent on your endpoints to have it forward logs to your OSSEC manager on your Security Onion machine.
https://github.com/Security-Onion-Solutions/security-onion/wiki/OSSEC
Some of the functionality (file access, removable devices) you are looking for is configurable within OSSEC. You can have a look here for more information:
You could also configure Windows Event Forwarding to forward logs to a subscription server and have OSSEC monitor and alert on those logs.
As far as monitoring files in email, you could look at the following if you want to perform automated analysis:
https://tribalchicken.com.au/technical/automated-mail-server-cuckoo-analysis-v2-0/
Otherwise, you should be able to pivot to a PCAP (CapMe, Wireshark, NetworkMiner) and see/extract the files for the particular email.
Bro also logs files it extracts from traffic to /nsm/bro/extracted.
Hope that helps!
Thanks,
Wes
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