Python's the most popular language on ScraperWiki, has the most 3rd party libraries, and is arguably the simplest to pick up. PHP's syntax is a little closer to Javascript though, so you personally might find that easier, if a little limiting in the long run. My advice: Just pick one and give it a go. We have lots of tutorials and documentation in all three languages (http://scraperwiki.com/docs), so you'll probably find you're up and running far quicker than you think.
Zarino