Google Groups no longer supports new Usenet posts or subscriptions. Historical content remains viewable.
Dismiss

What solvents dissolve PMMA?

14,943 views
Skip to first unread message

Mike VM

unread,
Jun 17, 2003, 4:53:08 PM6/17/03
to
Does anybody know where I could get information as to what common
solvents (IPA, methanol, acetone, etc.) dissolve (or don't dissolve)
PMMA?

For a more general question: What is the best resource on the Web for
finding out what solvents attack a given material?

Thanks,

Mike VM

jriegle

unread,
Jun 17, 2003, 5:38:55 PM6/17/03
to
Methylene Chloride for one. It is used in acrylic solvent cement.
John

"Mike VM" <mvan...@aol.com> wrote in message
news:a7edb004.03061...@posting.google.com...

William DiMenna

unread,
Jun 17, 2003, 6:49:18 PM6/17/03
to
It depends of the molecular weight of PMMA. Ethyl lactate dissolves PMMA
about 120000 mw. Dichlorobenzene is used for high mw used in e beam resists,
although there are other non-chlorinated solvents that work for high mw. Let
me check a few references/products and get back to you.
BILL D

"jriegle" <jri...@att.net> wrote in message
news:PTLHa.10991$3o3.7...@bgtnsc05-news.ops.worldnet.att.net...

Oliver 'Ojo' Bedford

unread,
Jun 18, 2003, 2:59:55 AM6/18/03
to
mvan...@aol.com (Mike VM) writes:

> Does anybody know where I could get information as to what common
> solvents (IPA, methanol, acetone, etc.) dissolve (or don't dissolve)
> PMMA?

I think Methyl ethyl ketone (2-butanone) will do.
Pure ethanol and pure water do not, but mixtures do.

> For a more general question: What is the best resource on the Web for
> finding out what solvents attack a given material?

Ullmann is always my first choice. Then there are some free databases
listing compatibility of polymers with common solvents, these
might also help. And, of course the Polymer Handbook.

You could also try to use (Hansen) solubility parameters, but this
is a bit more complicated.

Oliver

Frank Logullo

unread,
Jun 18, 2003, 12:16:03 PM6/18/03
to

"William DiMenna" <dime...@fidnet.com> wrote in message
news:EoKcneMHRpA...@fidnet.com...

> It depends of the molecular weight of PMMA. Ethyl lactate dissolves PMMA
> about 120000 mw. Dichlorobenzene is used for high mw used in e beam
resists,
> although there are other non-chlorinated solvents that work for high mw.
Let
> me check a few references/products and get back to you.
> BILL D
>
I don't think mol. wt. is a major factor. There are a lot of MMA copolymers
out there - some made for increased solubility in different solvents.
Lucite International has a resin booklet for Elvacite acrylic resins that
details this.
Frank


Dev Null

unread,
Jun 28, 2003, 5:50:53 PM6/28/03
to
mvan...@aol.com (Mike VM) wrote in
news:a7edb004.03061...@posting.google.com:

Anisol is a common PMMA solvent.

Frank Logullo

unread,
Jun 28, 2003, 6:13:30 PM6/28/03
to

"Dev Null" <dev...@foo.bar> wrote in message
news:Xns93A8B59D72...@216.168.3.44...

Lots of more common solvents dissolve PMMA. Copolymers are even more
soluble. Lucite International has an Elvacite acrylic resin pamphlet which
details.
Frank


dave....@web.de

unread,
Jun 30, 2003, 10:26:22 AM6/30/03
to
> Lots of more common solvents dissolve PMMA. Copolymers are even more
> soluble. Lucite International has an Elvacite acrylic resin pamphlet which
> details.
> Frank

chloroform "was" a good solvent. When i was a kid i used to take a lil
lump of plexiglas (R) and dissolved it in CHCl3 until it was a higher
viscosity liquid. This is what i used as glue to save money while
building the model airplanes and boats (Revell or so). Nowadays
chloroform seems to be a bit more poisonous than it was 25 years ago,
but if you know what you're doing, chloroform is perfect for
dissolving the pmma.

dave

Frank Logullo

unread,
Jun 30, 2003, 7:17:48 PM6/30/03
to

<dave....@web.de> wrote in message
news:82c9d2ee.03063...@posting.google.com...
When I was a kid, they had chloroform in cough medicine ;)
Frank
Also, pure PMMA is soluble in acetone, THF, MEK, ethyl acetate, acetonitrile
and insoluble in alcohols and ether. Several other solvents like toluene
give cloudy solutions.


sainty...@gmail.com

unread,
Jun 8, 2016, 9:43:42 AM6/8/16
to
chloroform

dr.ra...@gmail.com

unread,
Jun 19, 2016, 10:09:20 PM6/19/16
to
Dear Mike,
The solvents that dissolve PMMA are dimethylformamide (DMF) and Diethyl carbonate (DEC). DEC work even much better with that.
the non-solvents of PMMA are propylene carbonate (PC), ethylene carbonate (EC) and gamma buterolactone (GBL). They are not the all but the most, according to my on calculations which agree with Hansen solubility theory.
I hope this helps you in somewhat. and should you have any further inquiry I am happy to give a hand.


Good luck
Dr. Ra'id

asim....@gmail.com

unread,
Mar 4, 2017, 10:12:02 AM3/4/17
to
Hi.
I want to make some coatings apply on gravure machine.
I want know the best solvent to get minimum viscosity with maximum solids.
Regards

mohsink...@gmail.com

unread,
Mar 9, 2020, 2:30:20 PM3/9/20
to
PMMA easily dissolve in Acetone at room temperature and in DMF too

Isha Arora

unread,
Dec 1, 2020, 8:49:46 AM12/1/20
to
Can anyone please help me in knowing the mixing ratios for PMMA in THF

Ameer Khazal

unread,
Jun 17, 2022, 7:30:48 AM6/17/22
to
0 new messages