There is no reason to think that the constructible
universe is countable.
It is true that the definable power set of an
infinite set has the same cardinality as the
given infinite set when the axiom of choice
holds. This is in Kunen. But, the constructible
universe is formulated in relation to a given
model which represents the consistency assumption.
So, if two sets of the given model are such that
an uncountable infinity of membership relations
hold between respective pairs of their elements,
the definable membership relation obtained
from the pertinent Goedel function would be
uncountable. Hence, the constructible universe
would be uncountable.
That the constructible universe depends upon a
given model may be seen, for example, from Hamkins'
work in the links,
http://jdh.hamkins.org/every-model-embeds-into-own-constructible-universe/
http://arxiv.org/pdf/1207.0963v3.pdf
To the extent that the constructible universe is
"singular", the given model would be the one
"true model". But, one may only know that there
is a "true model" if set theory is consistent.
So, before you can talk about the countability
of *the* constructible universe you must know
which model is the actual V.