>> I don't think you can attribute your performance to sulfation - the
>> battery has to be almost dead and sitting for guite some time. Then it
>> won't accept a charge.
> "Sulfation" in a weak sense, in that, that's simply how a lead acid
> works (PbSO4 and Pb <--> Pb and PbO2), but that it's probably nonuniform
> enough to cause problems (high ESR) but apparently not beyond the point
> of no return.
> Tim
The equation we are interested in is
Pb(s) + PbO2(s) + 2H2SO4(aq) --> 2PbSO4(s) + 2H2O(l)
Both plates get sulfated. This is not bad if the battery gets fully charged
before the sulfur crystals have time to harden. Here are some articles that
describe it better:
BU-804b: Sulfation and How to Prevent it
Applying ways to minimize sulfation.
Sulfation occurs when a lead acid battery is deprived of a full
charge. This is common with starter batteries in cars driven in the
city with load-hungry accessories. A motor in idle or at low speed
cannot charge the battery sufficiently.
Electric wheelchairs have a similar problem in that the users might
not charge the battery long enough. An 8-hour charge during the
night when the chair is not being used is not enough. Lead acid must
periodically be charged 14 - 16 hours to attain full saturation.
This may be the reason why wheelchair batteries last only 2 years,
whereas golf cars with the identical battery deliver twice the
service life. Long leisure time allows golf car batteries to get a
full charge overnight. (See 403: Charging Lead Acid.)
Solar cells and wind turbines do not always provide sufficient
charge for lead acid banks, which can lead to sulfation. This
happens in remote parts of the world where villagers draw generous
amounts of electricity with insufficient renewable resources to
charge the batteries. The result is a short battery life. Only a
periodic fully saturated charge can solve the problem. But without
an electrical grid at their disposal, this is almost impossible.
An alternative solution is using lithium-ion, a battery that prefers
a partial charge to a full charge. However, Li-ion is more than
double the cost of lead acid. Although more expensive, the cycle
count is said to be cheaper than that of lead acid because of the
extended service life.
What is sulfation? During use, small sulfate crystals form, but
these are normal and are not harmful. During prolonged charge
deprivation, however, the amorphous lead sulfate converts to a
stable crystalline and deposits on the negative plates. This leads
to the development of large crystals that reduce the battery's
active material, which is responsible for the performance.
There are two types of sulfation: reversible (or soft sulfation),
and permanent (or hard sulfation). If a battery is serviced early,
reversible sulfation can often be corrected by applying an
overcharge to an already fully charged battery in the form of a
regulated current of about 200mA. The battery terminal voltage is
allowed to rise to between 2.50 and 2.66V/cell (15 and 16V on a 12V
mono block) for about 24 hours. Increasing the battery temperature
to 50 - 60C (122 - 140F) during the corrective service further helps
in dissolving the crystals.
Permanent sulfation sets in when the battery has been in a low
state-of-charge for weeks or months. At this stage, no form of
restoration seems possible; however, the recovery yield is not fully
understood. To everyone's amazement, new lead acid batteries can
often be fully restored after dwelling in a low-voltage condition
for many weeks. Other factors may play a role.
A subtle indication whether lead acid can be recovered or not is
visible on the voltage discharge curve. If a fully charged battery
retains a stable voltage profile on discharge, chances of
reactivation are better than if the voltage drops rapidly with load.
Several companies offer anti-sulfation devices that apply pulses to
the battery terminals to prevent and reverse sulfation. Such
technologies will lower the sulfation on a healthy battery, but they
cannot effectively reverse the condition once present. It's a "one
size fits all" approach and the method is unscientific.
Applying random pulses or blindly inducing an overcharge can harm
the battery by promoting grid corrosion. There are no simple methods
to measure sulfation, nor are commercial chargers available that
apply a calculated overcharge to dissolve the crystals. As with
medicine, the most effective remedy is to apply a corrective service
for the time needed and not longer.
While anti-sulfation devices can reverse the condition, some battery
manufacturers do not recommend the treatment as it tends to create
soft shorts that may increase self-discharge. Furthermore, the
pulses contain ripple voltage that causes some heating of the
battery. Battery manufacturers specify the allowable ripple when
charging lead acid batteries.
Last updated 2016-09-22
http://batteryuniversity.com/index.php/learn/article/sulfation_and_how_to_p
revent_it
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Discharge
In the discharged state both the positive and negative plates become
lead(II) sulfate (PbSO4), and the electrolyte loses much of its
dissolved sulfuric acid and becomes primarily water. The discharge
process is driven by the conduction of electrons from the negative
plate back into the cell at the positive plate in the external
circuit.
The total reaction can be written as
Pb(s) + PbO2(s) + 2H2SO4(aq) --> 2PbSO4(s) + 2H2O(l)
Sulfation and desulfation
Lead - acid batteries lose the ability to accept a charge when
discharged for too long due to sulfation, the crystallization of
lead sulfate.[27] They generate electricity through a double sulfate
chemical reaction. Lead and lead dioxide, the active materials on
the battery's plates, react with sulfuric acid in the electrolyte to
form lead sulfate. The lead sulfate first forms in a finely divided,
amorphous state, and easily reverts to lead, lead dioxide and
sulfuric acid when the battery recharges. As batteries cycle through
numerous discharges and charges, some lead sulfate is not recombined
into electrolyte and slowly converts to a stable crystalline form
that no longer dissolves on recharging. Thus, not all the lead is
returned to the battery plates, and the amount of usable active
material necessary for electricity generation declines over time.
Sulfation occurs in lead - acid batteries when they are subjected to
insufficient charging during normal operation. It impedes
recharging; sulfate deposits ultimately expand, cracking the plates
and destroying the battery. Eventually so much of the battery plate
area is unable to supply current that the battery capacity is
greatly reduced. In addition, the sulfate portion (of the lead
sulfate) is not returned to the electrolyte as sulfuric acid. It is
believed that large crystals physically block the electrolyte from
entering the pores of the plates. Sulfation can be avoided if the
battery is fully recharged immediately after a discharge cycle.[28]
A white coating on the plates may be visible (in batteries with
clear cases, or after dismantling the battery). Batteries that are
sulfated show a high internal resistance and can deliver only a
small fraction of normal discharge current. Sulfation also affects
the charging cycle, resulting in longer charging times, less
efficient and incomplete charging, and higher battery temperatures.
SLI batteries (starting, lighting, ignition; ie, car batteries)
suffer most deterioration because vehicles normally stand unused for
relatively long periods of time. Deep cycle and motive power
batteries are subjected to regular controlled overcharging,
eventually failing due to corrosion of the positive plate grids
rather than sulfation.
There are no known, independently verified ways to reverse
sulfation.[8][29] There are commercial products claiming to achieve
desulfation through various techniques (such as pulse charging), but
there are no peer-reviewed publications verifying their claims.
Sulfation prevention remains the best course of action, by
periodically fully charging the lead-acid batteries.
https://en.wikipedia.org/wiki/Lead%E2%80%93acid_battery
So when you go to Walmart or some other battery store, you may see racks of
batteries waiting to be sold. The reason they don't sulfate is because they
were fully charged before being placed on the racks, and they don't stay
there long enough to become discharged.