On Tuesday, 31 March 2015 01:26:00 UTC+11, Phil Hobbs wrote:
> On 03/30/2015 10:12 AM, Bill Sloman wrote:
> > On Monday, 30 March 2015 23:29:02 UTC+11, Phil Hobbs wrote:
> >> On 3/30/2015 1:51 AM, Bill Sloman wrote:
> >>> On Sunday, 29 March 2015 11:51:09 UTC+11, Phil Hobbs wrote:
> >>>> On 3/28/2015 12:36 PM, piglet wrote:
> >>>>> On 28/03/2015 15:00,
oldy...@yahoo.com wrote:
<snip>
It's not "iodide vapour" that interesting, but tungsten iodide vapour (which may have been what you meant) and that doesn't decompose "everywhere".
Tungsten chloride doesn't decompose below 1200C. Tungsten iodide still seems to form at 800C
http://www.digipac.ca/chemical/mtom/contents/chapter3/halogenlight.htm
In reality, there's an equilibrium between tungsten and iodine and tungsten iodide which is heavily biased towards tungsten iodide at low temperatures and towards the elements at high temperatures do a degree that's controlled by the enthalpy of formation
https://labs.chem.ucsb.edu/zakarian/armen/11---bonddissociationenergy.pdf
only lists the bond energy for W-F and W-Cl (548 and 4323 kjoule/mole). The entropy involved is obvious.
The point is that WI2, WI4 etc form away from the filament, and come apart close to the filament. The processes of formation and decomposition are fastest where the temperature is higher - closest to the filament.
Both processes may be going on "everywhere", but decomposition is a lot faster close to the filament, and even faster closer to hot spots on the filament. I did do my Ph.D. in chemical kinetics so I may be more conscious of the importance of reaction rates than you seem to be.
<snip>
> > Got any pictures? "Largeish" in the context of a coiled-coil
> > tungsten filament would probably only show up in an
> > electron-microscope photograph.
>
> Largish in the sense of "comparable to the wire radius".
If they stick out, they'll be cooler than the body of the filament - no resistance heating - and the tip won't grow as fast as surfaces closest to the filament.
> Someplace on the web, there was a great picture of a well-used BMW
> headlamp filament, but I couldn't find it again in a quick search. It
> had tungsten crystals comparable in size to the filament radius, which
> was _big_. You can probably find it in a few minutes if you look.
You couldn't find it, so my chances would be worse.
> >> The halide mechanism is thus sort-of regenerative, but its main
> >> purpose is to keep the very small envelope clean.
> >
> > True.
> >
> >> Normal low pressure bulbs reduce darkening by spreading the
> >> condensed tungsten over an area ~100x larger, but a bulb that big
> >> with the kind of internal pressure required to reduce diffusion
> >> would be very dangerous, and the internal convection loss would be
> >> gigantic.
> >
> > The halide regeneration was developed to beat that particular limit
> > - with the halogen in the gas mix you can get away with running the
> > filament hotter, and in a more compact envelope. If memory serves,
> > the scheme was originally developed to make better bulbs for car
> > head-lights and it was a while later before you could get tungsten
> > halogen bulbs for domestic lighting - and the first generation of
> > them showed their automotive origins by needing step-down
> > transformers to let them run at 12V.
>
> I remember "high intensity" desk lamps back in the '60s that used
> halogen bulbs. I think slide projectors had them very early too. Most
> bulbs used in projectors are low voltage to this day, because the
> coarser gauge filaments last a lot longer at the same temperature--lots
> more metal available per unit area.
Further reading says I got it wrong - the first tungsten halide bulbs were developed for aircraft beacon lights, and they moved into project lamps very early on.
The advantage of coarser gauge filaments can't be all that great - with transformer drive you can use pretty much any voltage you want, but while there are lower voltage bulbs available (for bicycle lights, for instance) nobody seems to be selling lower-than-12V bulbs for interior lighting.
My 240V halogen lamps for indoor lighting last two years - twice as long as the regular bulbs they replace, as well as delivering appreciably more light per watt consumed.
--
Bill Sloman, Sydney