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WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 1 of 7
Section 1 -CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
WD-40 AEROSOL
SYNONYMS
"61011 -7g", "61006 -60g", "61001 -150g", "61002 -255g", "61031 -275g",
"61003 -300g", "61009 -350g", "61032 -375g",
"61004 -425g", "61033 -500g"
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
¦
The use of a quantity of material in an unventilated or confined space
may result in increased exposure and an irritating
atmosphere developing. Before starting consider control of exposure by
mechanical ventilation.
Application is by spray atomisation from a hand held aerosol pack.
Lubricates, corrosion inhibitor, displaces moisture, penetrant, cleans
(spray).
SUPPLIER
Company: WD-40 Company Australia Pty Ltd
Address:
Level 2, Suite 23, 41 Rawson Street
Epping
NSW, 2121
Australia
Telephone:
+61 2 9868 2200
Emergency Tel: 1800 024 973
Fax:
+61 2 9869 7512
Section 2 -HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and
ADG Code.
RISK SAFETY
¦
Flammable. • Avoid contact with skin.
¦
Irritating to skin. • Wear suitable gloves.
¦
Risk of explosion if heated under • To clean the floor and all objects
contaminated by this
confinement. material, use water and detergent.
¦
Repeated exposure may cause skin • If swallowed, IMMEDIATELY contact
Doctor or Poisons
dryness and cracking. Information Centre. (show this container or
label).
¦
Vapours may cause drowsiness and • This material and its container must
be disposed of as
dizziness. hazardous waste.
Section 3 -COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
white spirit 8052-41-3. 45-50
paraffinic distillate, heavy, solvent-dewaxed (severe) 64742-65-0. 15-25
isoparaffins petroleum hydrotreated HFP 64742-47-8. 12-18
carbon dioxide 124-38-9 2-3
Section 4 -FIRST AID MEASURES
SWALLOWED
• Avoid giving milk or oils.
• Avoid giving alcohol.
• Not considered a normal route of entry.
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side
(head-down position, if possible) to maintain open airway and
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 2 of 7
Section 4 -FIRST AID MEASURES
prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with
reduced awareness; i.e. becoming unconscious.
EYE
¦
If aerosols come in contact with the eyes:
• Immediately hold the eyelids apart and flush the eye continuously for
at least 15 minutes with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and
away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
• Transport to hospital or doctor without delay.
• Removal of contact lenses after an eye injury should only be
undertaken by skilled personnel.
SKIN
¦
If solids or aerosol mists are deposited upon the skin:
• Flush skin and hair with running water (and soap if available).
• Remove any adhering solids with industrial skin cleansing cream.
• DO NOT use solvents.
• Seek medical attention in the event of irritation.
INHALED
¦
If aerosols, fumes or combustion products are inhaled:
• Remove to fresh air.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be
removed, where possible, prior to initiating first aid
procedures.
• If breathing is shallow or has stopped, ensure clear airway and apply
resuscitation, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform
CPR if necessary.
NOTES TO PHYSICIAN
¦
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or
related hydrocarbons:
• Primary threat to life, from pure petroleum distillate ingestion
and/or inhalation, is respiratory failure.
• Patients should be quickly evaluated for signs of respiratory distress
(e.g. cyanosis, tachypnoea, intercostal retraction,
obtundation) and given oxygen. Patients with inadequate tidal volumes or
poor arterial blood gases (pO2 50 mm Hg) should be
intubated.
• Arrhythmias complicate some hydrocarbon ingestion and/or inhalation
and electrocardiographic evidence of myocardial injury has
been reported; intravenous lines and cardiac monitors should be
established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
• A chest x-ray should be taken immediately after stabilisation of
breathing and circulation to document aspiration and detect
the presence of pneumothorax.
Section 5 -FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
¦
SMALL FIRE:
• Water spray, dry chemical or CO2
LARGE FIRE:
• Water spray or fog.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or
water course.
When any large container (including road and rail tankers) is involved
in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
• Liquid and vapour are flammable.
• Moderate fire hazard when exposed to heat or flame.
• Vapour forms an explosive mixture with air.
• Moderate explosion hazard when exposed to heat or flame.
Combustion products include: carbon dioxide (CO2), phosphorus oxides
(POx), sulfur oxides (SOx), other pyrolysis products typical
of burning organic material.
Contains low boiling substance: Closed containers may rupture due to
pressure buildup under fire conditions.
FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising
acids, chlorine bleaches, pool chlorine etc. as ignition may
result.
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 3 of 7
Section 5 -FIRE FIGHTING MEASURES
HAZCHEM
2YE
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
Section 6 -ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Wear protective clothing, impervious gloves and safety glasses.
• Shut off all possible sources of ignition and increase ventilation.
MAJOR SPILLS
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the
MSDS.
Section 7 -HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Prevent concentration in hollows and sumps.
SUITABLE CONTAINER
• Aerosol dispenser.
• Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
• Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
• Keep dry to avoid corrosion of cans. Corrosion may result in container
perforation and internal pressure may eject contents of
can.
• Store in original containers in approved flammable liquid storage
area.
• DO NOT store in pits, depressions, basements or areas where vapours
may be trapped.
• No smoking, naked lights, heat or ignition sources.
• Keep containers securely sealed. Contents under pressure.
Section 8 -EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m³ STEL ppm STEL mg/m³ Notes
___________
Australia Exposure
Standards
Australia Exposure
Standards
Australia Exposure
Standards
Australia Exposure
Standards
___________
white spirit (White
spirits)
white spirit (Petrol
(gasoline))
carbon dioxide
(Carbon dioxide in
coal mines)
carbon dioxide
(Carbon dioxide)
_______
12500
5000
_______
790
900
22500
9000
_______
30000
30000
_______
54000
54000
_______
(see
Chapter 16)
(see
Chapter 16)
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 4 of 7
Section 8 -EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTION
RESPIRATOR
•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN
143:2000 & 149:2001, ANSI Z88 or national equivalent)
EYE
¦
No special equipment for minor exposure i.e. when handling small
quantities.
OTHERWISE: For potentially moderate or heavy exposures:
• Safety glasses with side shields.
• NOTE: Contact lenses pose a special hazard; soft lenses may absorb
irritants and ALL lenses concentrate them.
HANDS/FEET
• No special equipment needed when handling small quantities.
• OTHERWISE:
• For potentially moderate exposures:
• Wear general protective gloves, eg. light weight rubber gloves.
OTHER
• The clothing worn by process operators insulated from earth may
develop static charges far higher (up to 100 times) than the
minimum ignition energies for various flammable gas-air mixtures. This
holds true for a wide range of clothing materials
including cotton.
• Avoid dangerous levels of charge by ensuring a low resistivity of the
surface material worn outermost.
BRETHERICK: Handbook of Reactive Chemical Hazards.
No special equipment needed when handling small quantities.
OTHERWISE:
• Overalls.
• Skin cleansing cream.
• Eyewash unit.
• Do not spray on hot surfaces.
ENGINEERING CONTROLS
¦
Engineering controls are used to remove a hazard or place a barrier
between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and
will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or
process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected
hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment.
Section 9 -PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Cloudy light amber flammable liquid with a sweet solvent odour; floats
on water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains carbon
dioxide propellant.
PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Floats on water.
State Liquid Molecular Weight Not Applicable
Melting Range (°C) Not Available Viscosity Not Available
Boiling Range (°C) Not Available Solubility in water (g/L) Immiscible
Flash Point (°C) 55 (TCC) pH (1% solution) Not Applicable
Decomposition Temp (°C) Not Available pH (as supplied) Not Applicable
Autoignition Temp (°C) Not Available Vapour Pressure (kPa) 724 max @21C
Upper Explosive Limit (%) Not Available Specific Gravity (water=1) 0.82
Lower Explosive Limit (%) Not Available Relative Vapour Density >1
(air=1)
Volatile Component (%vol) 78 Evaporation Rate Not Available
Section 10 -STABILITY AND REACTIVITY
CONDITIONS CONTRIBUTING TO INSTABILITY
• Elevated temperatures.
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 5 of 7
Section 10 -STABILITY AND REACTIVITY
• Presence of open flame.
• Product is considered stable.
• Hazardous polymerisation will not occur.
For incompatible materials -refer to Section 7 -Handling and Storage.
Section 11 -TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
¦
Irritating to skin. ¦
Repeated exposure may cause skin dryness and
cracking.
¦
Vapours may cause dizziness or
suffocation.
¦
Vapours may cause drowsiness and
dizziness.
TOXICITY AND IRRITATION
WD-40 AEROSOL:
¦
Not available. Refer to individual constituents.
WHITE SPIRIT:
¦
unless otherwise specified data extracted from RTECS -Register of Toxic
Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (human) TCLo: 600 mg/m³/8h Nil Reported
Oral (rat) LD50: >5000 mg/kg Eye (human): 470 ppm/15m
Inhalation (rat) LC50: >5500 mg/m³/4h Eye (rabbit): 500 mg/24h Moderate
¦
for petroleum:
This product contains benzene which is known to cause acute myeloid
leukaemia and n-hexane which has been shown to metabolize to
compounds which are neuropathic.
This product contains toluene.
This product contains ethyl benzene and naphthalene from which there is
evidence of tumours in rodents
Carcinogenicity: Inhalation exposure to mice causes liver tumours, which
are not considered relevant to humans.
white spirit, as CAS RN 8052-41-3
CARCINOGEN
Crude oil International Agency for Research on Cancer Group 3
(IARC) -Agents Reviewed by the IARC
Monographs
Section 12 -ECOLOGICAL INFORMATION
This material and its container must be disposed of as hazardous waste.
Ecotoxicity
Ingredient
WD-40 Aerosol
Persistence:
Water/Soil
No Data
Persistence: Air
No Data
Bioaccumulation Mobility
Available Available
white spirit No Data
Available
No Data
Available
Section 13 -DISPOSAL CONSIDERATIONS
• DO NOT allow wash water from cleaning or process equipment to enter
drains.
• It may be necessary to collect all wash water for treatment before
disposal.
• In all cases disposal to sewer may be subject to local laws and
regulations and these should be considered first.
• Where in doubt contact the responsible authority.
• Consult State Land Waste Management Authority for disposal.
• Discharge contents of damaged aerosol cans at an approved site.
• Allow small quantities to evaporate.
• DO NOT incinerate or puncture aerosol cans.
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 6 of 7
Section 14 -TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM:
2YE (ADG7)
ADG7:
Class or Division 2.1 Subsidiary Risk: None
UN No.: 1950 Packing Group: None
Special Provision: 63, 190, 277, 327 Limited Quantity: See SP 277
Portable Tanks & Bulk None Portable Tanks & Bulk None
Containers Containers
-Special
Instruction: Provision:
Packagings & IBCs PP17,
PP87, L2 Packagings & IBCs P003,
LP02
Packing Instruction: Special Packing
Provision:
Name and Description: AEROSOLS
Land Transport UNDG:
Class or division 2.1 Subsidiary risk: None
UN No.: 1950 UN packing group: None
Shipping Name:AEROSOLS
Air Transport IATA:
UN/ID Number: 1950 Packing Group: -
Special provisions: A145
Shipping Name: AEROSOLS, FLAMMABLE
Maritime Transport IMDG:
IMDG Class: 2 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F-D, S-U Special provisions: 63 190 277 327 344 959
Limited Quantities: See SP277
Shipping Name: AEROSOLS
Section 15 -REGULATORY INFORMATION
POISONS SCHEDULE None
REGULATIONS
Regulations for ingredients
white spirit (CAS: 8052-41-3) is found on the following regulatory
lists;
"Australia Exposure Standards","Australia Hazardous
Substances","Australia Inventory of Chemical Substances
(AICS)","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP)
-Appendix E (Part 2)","IMO IBC Code Chapter 17: Summary of
minimum requirements","IMO Provisional Categorization of Liquid
Substances -List 2: Pollutant only mixtures containing at least
99% by weight of components already assessed by IMO","International
Council of Chemical Associations (ICCA) -High Production
Volume List"
No data for WD-40 Aerosol (CW: 1950-6)
Section 16 -OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
isoparaffins petroleum hydrotreated 64742-47-8, 64742-82-1, 8052-41-3,
1030262-12-4,
HFP 101795-05-5
¦
Classification of the preparation and its individual components has
drawn on official and authoritative sources as well as
continued...
WD-40 AEROSOL
Chemwatch Independent Material Safety Data Sheet
Issue Date: 29-Jun-2010 CHEMWATCH 1950-6
C9317EC Version No:12
CD 2011/2 Page 7 of 7
Section 16 -OTHER INFORMATION
independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found
at:
www.chemwatch.net/references.
¦
The (M)SDS is a Hazard Communication tool and should be used to assist
in the Risk Assessment. Many factors determine whether
the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes
of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be
reproduced by any process without written
permission from CHEMWATCH. TEL
(+61 3) 9572 4700.
Issue Date: 29-Jun-2010
Print Date: 28-Jul-2011
This is the end of the MSDS.