There's a couple different themes you've mentioned in your message:
If you are after native Scala framework for RESTful web services you could take a look at
https://github.com/jdegoes/blueeyesIf you want to map objects to XML and back, you could try
http://scalaxb.org/ but it supports schema-first devlopment only (ie generates Scala sources from XSD)
If you want to go into opposite direction, you could look for some Java based tools that operate on binary classes. I had a quick look at JAXB tools for Java and it appears that class first development depends on processing Java sources, so they would not be useful for you.
Finally, if you need to validate XML files against XSD schema programatically, you could use javax.xml.valiation facility which as been part of Java JRE since release 1.5.
Cheers,
Rafał