Can't make any suggestions with respect to online material but agree with Ben that the Coursera Scala course would be worth doing.
I would suggest you take a piece of code that your colleagues are familiar with from your code base, naively convert it to Scala and then iteratively improve it using different features of Scala. So if the code was in Java, the first version would be a very Java like version of it (but written in Scala - I think IDEA can do this for you) so you can just focus on the Scala syntax like, val, var, def, variables names before types, return type at end, how the class constructors work, traits instead of interfaces, arrays, generics. You could even keep the Java collections at first.
Then you can apply some straightforward simplifications like case classes, automatic getters and setters, type inferencing and various types of syntactic sugar. Next Scala collections, discussion on immutability and use of the standard collection methods (eg map, filter) - might need an intro to closures and function literal syntax and more syntactic sugar. Warn them about the scary method signatures of some of the collection methods if they look at the Scala doc too closely
Things like pattern matching, use of Options and the for loop syntax will likely arise next and then you could look at how implicits work, conversion to/from java collections and basic pimp my class examples.
At the end of this they should have a basic feel for how common programming tasks would be mapped to Scala in a reasonably idiomatic way. The next step of looking at functional programming is a bigger learning curve and you need to decide how far down that road you want to go. The Coursera course is a good intro for the functional side of things and use of more of the collection methods.
Maybe a bit more work than going through already existing material but working with real code is a good way to learn, provides a context to discuss pros and cons of various way of solving a problem and gives examples that can be referred to later.
Bryan