U-238 Fast Fission

[Leda Billock]

Fast fission is fission that occurs when a heavy atom absorbs a high-energy neutron, called a fast neutron, and splits. Most fissionable materials need thermal neutrons, which move more slowly.

Fast neutron reactors use fast fission to produce energy, unlike most nuclear reactors. In a conventional reactor, a moderator is needed to slow down the neutrons so that they are more likely to fission atoms. A fast neutron reactor uses fast neutrons, so it does not use a moderator. Moderators may absorb a lot of neutrons in a thermal reactor, and fast fission produces a higher average number of neutrons per fission, so fast reactors have better neutron economy making a plutonium breeder reactor possible. However, a fast neutron reactor must use relatively highly enriched uranium or plutonium at the reactor startup so that the neutrons have a better chance of fissioning atoms.

Some atoms, notably uranium-238, do not usually undergo fission when struck by slow neutrons, but do split when struck with neutrons of high enough energy.[1] The fast neutrons produced in a hydrogen bomb by fusion of deuterium and tritium have even higher energy than the fast neutrons produced in a nuclear reactor. This makes it possible to increase the yield of any given fusion weapon by the simple expedient of adding layers of cheap natural (or even depleted) uranium. Fast fission of uranium-238 provides a large part of the explosive yield, and fallout, in many designs of hydrogen bomb.

The higher the energy of the state that undergoes nuclear fission, the more likely a symmetric fission is, hence as the neutron energy increases and/or the energy of the fissioning atom increases, the valley between the two peaks becomes more shallow; for instance, the curve of yield against mass for 239Pu has a more shallow valley than that observed for 235U, when the neutrons are thermal neutrons. The curves for the fission of the later actinides tend to make even more shallow valleys. In extreme cases such as 259Fm, only one peak is seen.[citation needed]

Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.

In a fission nuclear reactor, uranium-238 can be used to generate plutonium-239, which itself can be used in a nuclear weapon or as a nuclear-reactor fuel supply. In a typical nuclear reactor, up to one-third of the generated power comes from the fission of 239Pu, which is not supplied as a fuel to the reactor, but rather, produced from 238U.[5] A certain amount of production of 239
Pu from 238
U is unavoidable wherever it is exposed to neutron radiation. Depending on burnup and neutron temperature, different shares of the 239
Pu are converted to 240
Pu, which determines the "grade" of produced plutonium, ranging from weapons grade, through reactor grade, to plutonium so high in 240
Pu that it cannot be used in current reactors operating with a thermal neutron spectrum. The latter usually involves used "recycled" MOX fuel which entered the reactor containing significant amounts of plutonium[citation needed].

238U can produce energy via "fast" fission. In this process, a neutron that has a kinetic energy in excess of 1 MeV can cause the nucleus of 238U to split. Depending on design, this process can contribute some one to ten percent of all fission reactions in a reactor, but too few of the average 2.5 neutrons[6] produced in each fission have enough speed to continue a chain reaction.

238U can be used as a source material for creating plutonium-239, which can in turn be used as nuclear fuel. Breeder reactors carry out such a process of transmutation to convert the fertile isotope 238U into fissile 239Pu. It has been estimated that there is anywhere from 10,000 to five billion years worth of 238U for use in these power plants.[7] Breeder technology has been used in several experimental nuclear reactors.[8]

By December 2005, the only breeder reactor producing power was the 600-megawatt BN-600 reactor at the Beloyarsk Nuclear Power Station in Russia. Russia later built another unit, BN-800, at the Beloyarsk Nuclear Power Station which became fully operational in November 2016. Also, Japan's Monju breeder reactor, which has been inoperative for most of the time since it was originally built in 1986, was ordered for decommissioning in 2016, after safety and design hazards were uncovered, with a completion date set for 2047. Both China and India have announced plans to build nuclear breeder reactors.[citation needed]

The Clean And Environmentally Safe Advanced Reactor (CAESAR), a nuclear reactor concept that would use steam as a moderator to control delayed neutrons, will potentially be able to use 238U as fuel once the reactor is started with Low-enriched uranium (LEU) fuel. This design is still in the early stages of development.[citation needed]

Natural uranium, with 0.711% 235
U
, is usable as nuclear fuel in reactors designed specifically to make use of naturally occurring uranium, such as CANDU reactors. By making use of non-enriched uranium, such reactor designs give a nation access to nuclear power for the purpose of electricity production without necessitating the development of fuel enrichment capabilities, which are often seen as a prelude to weapons production[citation needed].

The opposite of enriching is downblending. Surplus highly enriched uranium can be downblended with depleted uranium or natural uranium to turn it into low-enriched uranium suitable for use in commercial nuclear fuel.

238U from depleted uranium and natural uranium is also used with recycled 239Pu from nuclear weapons stockpiles for making mixed oxide fuel (MOX), which is now being redirected to become fuel for nuclear reactors. This dilution, also called downblending, means that any nation or group that acquired the finished fuel would have to repeat the very expensive and complex chemical separation of uranium and plutonium process before assembling a weapon.[citation needed]

Most modern nuclear weapons utilize 238U as a "tamper" material (see nuclear weapon design). A tamper which surrounds a fissile core works to reflect neutrons and to add inertia to the compression of the 239Pu charge. As such, it increases the efficiency of the weapon and reduces the critical mass required. In the case of a thermonuclear weapon, 238Ucan be used to encase the fusion fuel, the high flux of very energetic neutrons from the resulting fusion reaction causes 238U nuclei to split and adds more energy to the "yield" of the weapon. Such weapons are referred to as fission-fusion-fission weapons after the order in which each reaction takes place. An example of such a weapon is Castle Bravo.

The larger portion of the total explosive yield in this design comes from the final fission stage fueled by 238U, producing enormous amounts of radioactive fission products. For example, an estimated 77% of the 10.4-megaton yield of the Ivy Mike thermonuclear test in 1952 came from fast fission of the depleted uranium tamper. Because depleted uranium has no critical mass, it can be added to thermonuclear bombs in almost unlimited quantity. The Soviet Union's test of the Tsar Bomba in 1961 produced "only" 50 megatons of explosive power, over 90% of which came from fusion because the 238U final stage had been replaced with lead. Had 238U been used instead, the yield of the Tsar Bomba could have been well above 100 megatons, and it would have produced nuclear fallout equivalent to one third of the global total that had been produced up to that time.

The decay chain of 238U is commonly called the "radium series" (sometimes "uranium series"). Beginning with naturally occurring uranium-238, this series includes the following elements: astatine, bismuth, lead, polonium, protactinium, radium, radon, thallium, and thorium. All of the decay products are present, at least transiently, in any uranium-containing sample, whether metal, compound, or mineral. The decay proceeds as:

While 238U is minimally radioactive, its decay products, thorium-234 and protactinium-234, are beta particle emitters with half-lives of about 20 days and one minute respectively. Protactinium-234 decays to uranium-234, which has a half-life of hundreds of millennia, and this isotope does not reach an equilibrium concentration for a very long time. When the two first isotopes in the decay chain reach their relatively small equilibrium concentrations, a sample of initially pure 238U will emit three times the radiation due to 238U itself, and most of this radiation is beta particles.

As already touched upon above, when starting with pure 238U, within a human timescale the equilibrium applies for the first three steps in the decay chain only. Thus, for one mole of 238U, 3106 times per second one alpha and two beta particles and a gamma ray are produced, together 6.7 MeV, a rate of 3 μW.[10][11]

238U abundance and its decay to daughter isotopes comprises multiple uranium dating techniques and is one of the most common radioactive isotopes used in radiometric dating. The most common dating method is uranium-lead dating, which is used to date rocks older than 1 million years old and has provided ages for the oldest rocks on Earth at 4.4 billion years old.[14]

Uranium emits alpha particles through the process of alpha decay. External exposure has limited effect. Significant internal exposure to tiny particles of uranium or its decay products, such as thorium-230, radium-226 and radon-222, can cause severe health effects, such as cancer of the bone or liver.

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