This is another of the toys I've been working on. This one still needs a bit more work. I had the I2C attached to the wrong pins on the Shield side, and I need to add the Arduino ICSP connector as a lot of shields use that extensively. It's also only a small mod away from allowing you to stick an Arduino proper on the underside of the board if built with pass through pins so you can make an Arduino sandwich that fits into an RC2014 slots (even if it occupies several depthwise).
The PIO side is a Z80PIO (as it can do per bit direction). The i2c side is a PCF8584 and still needs further debug - for one I had SDA/SCL on the wrong Arduino pins. The D0/D1 lines of the Arduino can be jumpered to the PIO or to the RX/TX lines on the RC2014 bus.
The basics work however, and it's currently providing an SD card under Fuzix.

Alan