Up until a few days ago, it was not possible to define different floppy drive types under RomWBW. So, you are not doing anything wrong, it just isn't possible in the version of RomWBW you are using.
If you want to try the latest RomWBW Development Snapshot (see
Releases Page), you can define the floppy drive types independently. To use a 3.5" drive as FD0 and a 5.25" drive as FD1, you can put this in your config file:
FD0TYPE .SET FDT_3HD ; FD 0: DRIVE TYPE: FDT_[3DD|3HD|5DD|5HD|8]
FD1TYPE .SET FDT_5HD ; FD 1: DRIVE TYPE: FDT_[3DD|3HD|5DD|5HD|8]
You will need to build a custom ROM after making these changes. Since this is a new feature, I would appreciate your feedback.
Thanks,
Wayne