The Z85C30 SCC is two port, the other two will be the Z180 ports. Looking at the 1488/1489 that looks like RS232 to me (and now I've found the manual that confirms it)
Seems to be a space to add an RTC (crystal, chips, battery).
Doesn't look like there is enough RAM to run CP/M (32K isn't going to cut it) but from the extra pins I imagine you can stick a 128K RAM in there.
You'd also need to populate J7 to attach some kind of disk or other storage to it. There's enough info in the user manual for that as there is a schematic of one of the I/O expansion options which in turn gives you the info needed.
Incredibly you can still buy them new ... for £450 each cased!
Alan