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"Nevus" <csock...@gmail.com> wrote in message
news:3043cb79-44b8-4f3c...@v17g2000yqv.googlegroups.com...
(Edited) "Phosphoric acid may be used as a "rust converter", by direct
application to rusted iron, steel tools, or surfaces. The phosphoric
acid converts reddish-brown iron(III) oxide (rust) to black ferric
phosphate, FePO4........After treatment, the black ferric-phosphate
coating can be scrubbed off, leaving a fresh metal surface...... The
black phosphate coating can also be left in place, where it will
provide moderate further corrosion resistance. (Such protection is
also provided by the superficially similar Parkerizing and blued
electrochemical conversion coating processes.)"
I thought I had either "blued" my hardware or adding the CLR has
somehow stripped the shine away. I guess I didn't think the hardware
was completely covered in rust so I wasn't expecting a complete
coating of black. I'll try soaking overnight this evening.
I CLR'd a few zinc plated parts, and believe me, it can strip that
zinc of right off and down to the mild steel beneath it. And before
completely going that far, it turns the surface zinc black; and that
black stuff does *not* rinse off easily --- if at all. You will have
to get out jeweler's rouge and a buffing wheel to handle it. It has
happened to me, so I'm not just speculating here.
CLR will react with zinc plated parts almost instantly. You can see
it start to turn black-ish, and small bubbles start to form. At that
point, it's too late. Don't put zinc plated parts anywhere near CLR.
You can use CLR on 'rusty' (pitted through) nickel plated steel, but
forget about using it on zinc plated steel.
If you want to see a similar, but even worse reaction, try using CLR
on Aluminum (no, don't try it).
This reaction I am talking about (above) has nothing to do with
converting brown Iron III Oxide to black Ferric-Phosphate. Your
chemical statement is correct, but it doesn't apply when dealing with
zinc or aluminum reacting with CLR.
Cheers,
--- Rob
On Sat, 11 Dec 2010 06:35:44 -0800 (PST), Nevus <csock...@gmail.com>
wrote:
I took the expeirment farther lsat night. I placed some leg bolts,
small screws, and two post screws in the phosphoric acid overnight.
Early on the acid bubbled and the parts got a little shiny. This
morning, all dark/blue coated (ferric phosphate?). It does not wash
off with water or toothbrush. :(
I'll glady take more tips, brand recs etc. I'm starting to think I
need to just buy new stuff.
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"Ron - NYP" <rons...@optonline.net> wrote in message
news:4d036f44$0$20158$607e...@cv.net...