Although you really should shift into the small cog before trying to rest that chain (as I was reminded this afternoon when I did a quixotic wheel swap to avoid having a blowout on my rear tire on a trip to downtown Oakland to pay my water bill). If the chain isn't lined up with the inside of the seat stay, said chain may pop right back off.
PeterAdler
who saw Panaracer's red anti-puncture belt visible through large areas of the tread on one of the few tires he's actually ridden to pieces, and finally faced up to reality in
Berkeley, CA/USA