When I started riding my bike with the polished silver Pacenti Brevet rims, the RH front canti definitely squealed.
The smoothness of the polished brake web was definitely the major contributor, which I addressed by using some contact cement to attach pad-shaped emory paper to the brake pads' contact faces, and did some light braking on the downslope in front of the house until I got what looked like a nice wear-in of the polished finish. I did the back too for aesthetic symmetry.
Cantilever squeal/squawk does have many causes, as others have pointed out. It helps to imagine that, until the wheel is locked, friction by a brake can be a state of oscillation, like a violin string being played by the horsehair of a bow. A Google AI response to that as a question says:
Sliding friction (or kinetic friction) is not an oscillation in itself. Rather, it is a constant or resistive force that opposes motion. However, when sliding
friction interacts with elasticity, it often leads to physical systems entering a state of oscillation.
This has helped me wrap my head around how pads (in density or coefficient of friction), brake arms, rims, headsets, and forks themselves can contribute to a result of noise as the rim rotates against the contacting brake pads. Mathias' experience mirrored mine when my shop sold that Cannondale model. Its fork was made for serious touring loads, on those large-diameter aluminum frames, seriously reducing both the frame and fork from bearing any of the oscillation the front braking produced and without the weight of a load to damp things, the squawk was nearly constant
The slight difference in the lower race bearing surface of a headset could sometimes be enough to quiet those bikes when nothing else worked, but it was very rider and bike-size-specific. I would have one (small for me) finally braking quietly, then the customer would come to retrieve, and it would sqawk on the way to their car with them riding it.
Andy Cheatham
Pittsburgh