The first and obvious thing to do is measure the tube, be it with calipers or a measuring tape for the circumference, divided by 3.14 for the diameter. Even a string and a ruler will do.
The way I understand the seat tube is it's only ovalized at the very bottom where it joins the bottom bracket, for rigidity. Where the FD goes it's round it should still be the round 28.6 as Riv states. I have certain vintage Campy 28.6 clamp on FD's that don't fit my Bombadil perfectly, even though they're both 28.6. Who 'ya gonna call ? Ghost-busters ! (((((( :-) )))))
All the Riv Atlantis photos of the last model shows a shim being used for the FD.