Hi,
TL;DR: the operator will never change these credentials
When a new cluster is deployed, a secret is created and then mounted to the pods. When RabbitMQ starts and decides it is a fresh node (there is no previous state), it will create a user with these credentials.
From now on, the Operator will not change that secret and even if you do, RabbitMQ will ignore these changes because the nodes have been initialized already.
You can use standard RabbitMQ methods to create and manage users, such as rabbitmqctl or the Management API.