For the purposes of isolating Qubes traffic on your home network...
Got on IRC chat with some Whonix folks and got the answers I needed for this.
To clarify, I wanted to know if there is any benefit to configuring pfsense (or any firewall/router) so that each Qubes box is on its own VLAN. The answer I got was yes. One such benefit would be to make it more difficult for an attacker to jump from my son's Win10 box, which has god knows what installed on it, to my Qubes systems.