Hi all -
Good discussion and a couple of clarifications.
1. The ability to use biochemical oxygen demand (BOD) and carbonaceous BOD (CBOD) interchangeably depends on the amount of ammonia in the system and its oxidation rate (nitrification). If nitrogenous BOD (NBOD) is low, BOD and CBOD can be used interchangeably. To correctly measure CBOD, an inhibitor is used in the laboratory analysis to suppress nitrification so that the BOD measurement is only reflecting oxidation of carbon. CBOD computations in the model are therefore only applied only to carbon in the system and NBOD computations are handled separately via the ammonia compartment. If you have a system with high NBOD, an assumption that BOD = CBOD will not be correct and you will overestimate deoxygenation of the system since the model is already accounting for oxygen losses due to nitrification elsewhere (i.e., conversion of ammonia to nitrate based on waterbody specific nitrification rate).
2. The second comment is on the conversion of CBOD5 to CBOD ultimate, which has already been adequately described by Adam using equation 80 in the qual2kw manual (note: this is equation 75 in the updated manual on the
qual2k.com website). The basis here is that a 5-day test does not reflect the overall ultimate oxygen demand exerted by material in the water and thus you use the 5-day to ultimate correction (because in a lab/bottle test you can't run the sample to 0). Alternatively, you could use 20-day BOD analysis (with nitrogen inhibition) to closely approximately CBOD ultimate, which we have done in past work.
3. Finally, the use of fast and slow CBOD in the model would conventionally be used to represent different types/sources of CBOD. A good example would be a river that has both a municipal sewage discharge (i.e., relatively labile or fast carbon oxidation) and another from a discharge like a paper/pulp mill that would have slow carbon oxidation (refractory/recalcitrant).
Hope that helps,
Kyle