Hello Stefano,
With python packages and pip, there are usually two folders, one for the python libraries and one for the python executables. When a package is installed to a default location, the folder with the python executables will be copied to the desired location, but in this case since you installed to /opt/qiime/, I am assuming that there's a bin folder in /opt/qiime/python/bin (or maybe something like /opt/qiime/bin?), where all these scripts are located, add this path to the $PATH environment variable, I think that should do it. Else let me know what you find in /opt/qiime/...
Thanks!
Yoshiki.